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Lightly spray a bundt pan with cooking spray.
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Begin by layering macadamia nuts, coconut, pineapple, and rolls. Repeat several times until all the ingredients (except the butter and brown sugar) have been used.
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In a small saucepan, melt butter and sugar over medium-high heat. Once the mixture comes to a boil, stir and boil for one minute, and then remove from heat. Pour it over the top of your dough with nuts, coconut, and pineapple.
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Let mixture rise until it reaches the top of the pan, 1-2 hours.
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Bake at 350 degrees for 35 minutes.
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Once removed from oven, let sit for 10 minutes. Then invert onto serving plate, and let sit another ten minutes with the pan on top. Then carefully remove the pan.
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Serve warm or at room-temperature.